Relationship of ostracode abundance and taphonomy to environmental variables on the Luiche Delta Platform, Lake Tanganyika, East Africa

Jana M. Van Alstine1, Andrew S. Cohen1 and Kiram E. Lezzar2
1Department of Geosciences, University of Arizona, Tucson, 85721, AZ
2Department of Geology, Syracuse University
Email: janava@geo.arizona.edu

Tanganikan subfossil ostracodes from Lake Tanganyika accumulated over the past 50 years in surficial sediment were analyzed in order to examine relationships between taphonomic, subfossil abundance, and environmental variables, and identify variables of taphonomic potential value for paleoclimate reserach. Samples were taken from five northeast-southwest transects, shallow to deep profiles,across the Luiche Delta Platform in the Kigoma region of Lake Tanganyika, Tanzania. Ostracode valves were examined for redox staining, breakage, and abundance, and compared against depth, geography, proximity to river mouth, and total organic carbon. Strong relationships were shown to exist between the taphonomic and environmental variables with this study, revealing a complex system of associations on the delta platform. In particular, a strong correlation between vavle breakage and water depth was shown by this research. The exponential regression produced by this relationship makes it possible to generate a paleo-lake level curve for Lake Tanganyika using core samples taken in 1999 with the Nyanza Project.

Soil characterization at the World's Fair mine site, Patagonia mountains, Santa Cruz County, SE Arizona: Implications for baseline metal transport during storm runoff events

Kelly L Ashton1 and Oscar A. Duarte2
1College of Agriculture and Life Sciences, University of Arizona, Tucson, Arizona 85721
2US Geological Survey, ENRB, Tucson, Arizona 85719
Email: kashton@usgs.gov

The World's Fair Mine, located in the Patagonia Mountains, SE Arizona, produced just over $1,000,000 in ore by the early turn of the century (1915). The reported workings yielded silver, gold, lead, and copper ores in the form of lead-silver sulfides, tetrahedrite, along with minor chalcocite and silver-bearing stibnite. The target mineralizing system occurs as N. - S. trending quartz-barite veins hosted in a body of Cretaceous-age quartz diorite and rhyolite. The altered area ranges from 15-35 ft wide and is closely associated with a rhyolite dike that crosscuts the diorite. The vein is exposed for approximately 1000 ft down the dip slope; 600 ft of the vein has been excavated during the development of the mine. Currently, the mine site is abandoned and is part of a cluster of deposits found in the upper portions of Alum Gulch. The World's Fair Mine site has been identified as a contributor to the degraded condition of the Alum Gulch Watershed. The objective of this study was to characterize the soils and exposed waste rock material in the vicinity of the mine site with respect to their pH, mineralogy, acid generating potential, and trace element content and evaluate their impact on storm runoff in the watershed.

A portion of the area is underlain by a thin, rocky soil horizon representing undisturbed soils developed over country rock (diorite) and mineralized but heavily oxidized vein and selvage zones (altered rhyolite and quartz vein); segments of the lower slopes hosting the mineralized veins are marked by adits, shafts, and dissected waste-rock piles. Several traverses were selected to cross the country rock, undisturbed oxidized vein segment, and the disturbed waste rock piles. Composite samples were obtained at approximately 10 ft intervals across structure. Preliminary analysis of soils show that: 1) pH of soils overlying diorite country rock, altered diorite/rhyolite vein and selvage showed slightly acidic values (~6- 5.5). The soil pH of waste rock was considerably lower at around 3.6; 2) selected metals (Zn, Pb, Ag, Cu, Fe, Al, Cd) and trace element concentrations were highly variable in soils overlying oxidized vein material and waste rock but generally elevated. Oxidized vein material anomalous values were comparable to waste rock samples. Both sample sources were an order of magnitude greater than the soils overlying unmineralized country rock; 3) acid generation potential was negligible (neutral) in the soils of country rock and oxidized vein material, however, high acid generating potential was noted in waste rock samples.

Although further testing is warranted, preliminary data suggest that surface exposures of weathered mineralized soils and rock materials may contain elevated metal concentration similar to waste rock, however neutral to near-neutral pH conditions in intermittent waters in contact with the site preclude metals release and transport. This stands in contrast to the acidification of waters in contact with pyrite-bearing waste rock and accompanying dissolution of resident metal species.

Experimentally derived constraints on calcareous lacustrine fossil preservation following the Chicxulub acid trauma

J.V. Bailey1, A.S. Cohen1 and D.A. Kring2
1Department of Geosciences, University of Arizona, Tucson, AZ 85721-0077
2Department of Planetary Sciences, Lunar and Planetary Laboratory, University of Arizona ,Tucson, AZ 85721
Email: jbailey@jupiter.lpl.arizona.edu

The end-Cretaceous Chicxulub impact event, which occurred on a shallow marine shelf, produced an estimated 10 to 1000 GT of sulfur oxides, which were injected into the stratosphere as part of a globally-distributed vapor-rich plume. These sulphate aerosols eventually settled to the troposphere from which they promptly fell as acid rain. Whereas the deep ocean probably had a buffering capacity able to withstand the most extreme estimates of impact-generated acid rain fallout, the acid's effect on shallow water systems such as lakes, rivers, and shallow epicontinental seas, is far less certain. Some workers have suggested acid rain as a possible K/T extinction mechanism. Potentially, such an influx of acid could also affect fossil preservation by dissolution of calcareous remains at the surface and by the removal of buried remains via the leaching action of acidic groundwater.

We investigated the effects of hypothetical acid traumas on the preservation of buried lacustrine microfossils through a series of dissolution experiments. Because factors such as lake size, catchment area, precipitation, local humic acid production, and natural buffering capacity strongly influence a lake's resistance to acidification, the effect of the Chicxulub acid trauma on any particular Cretaceous paleolake would be influenced by the lake's initial conditions and the magnitude and duration of the acid input. Our experimental setup and conditions were designed to test the preservation potential of sediments from a variety of shallow water environments, which were subjected to a range of acidification conditions. Plastic tanks, filled with lake mud and ~12L of water, served as proxies for the sediment-water interface of several hypothetical acidified paleolakes. Modern ostracod carapaces were added to the sediment at depths of 1 cm, 5 cm, and 10 cm. In order to simulate a range of initial lake alkalinity and bedrock buffering conditions, the inorganic carbon content of the sediment (1, 10, and 20% CaCO3) was varied. Differing sulfuric acid treatments (pH 1.9, 3 and 4) were used in combination with each buffering treatment, with daily water changes to maintain acidity conditions. Four cores were taken from each tank 3, 12, 42, and 150 days after the initial acidification. Post-treatment ostracod abundances were determined by light microscopy and taphonomic condition of the valves was determined using electron microscopy. Carapace recovery was measured as a function of time, burial depth, inorganic carbon of the sediment, and pH of the water. Presence of carapaces showed a strong positive correlation with the amount of inorganic carbon in the tank's sediments. Of 108 total recovered core sections, 31 contained no carapaces. Of the 31 core sections with no carapace recovery, 26 were from tanks with the lowest (1% CaCO3) buffering capacity. Carapace recovery also showed a weak negative correlation with increasing time, lower pH, and shallowing depth. These data suggest that buffering capacity, rather than pH, time, and burial depth, is the primary mitigating factor in microfossil preservation. Buffering capacity may also have determined the survival of organisms with calcareous or Ca-phosphate skeletons in lakes and other shallow water settings at the K/T boundary. Because buffering capacity is governed by the mineralogical composition of the bedrock, we predict that survival of lacustrine organisms and preservation of calcareous lacustrine fossils would have been much higher in lakes with calcareous catchments, versus poor preservation in lakes underlain by black shales or granitic rocks.

Our results suggest that the biostratigraphy of fossils studied from K/T boundary shallow water sediments should be viewed within the context of local fossil preservation conditions, including the paleowatershed's bedrock composition. Furthermore, the survivability of shallow-water taxa, may be intimately related to the paleogeology and buffering capacity of their local habitat.

Debris aprons and channels in the Reull Vallis region of Mars

Daniel C. Berman1,2, William K. Hartmann2 and David A. Crown2,
1Department of Geosciences, University of Arizona, Tucson, AZ 85721
2Planetary Science Institute, 620 N. 6th Ave., Tucson, AZ 85705
Email: bermandc@geo.arizona.edu.

The highlands to the east of the Hellas impact basin in the southern hemisphere of Mars contain a variety of complex, interacting geologic structures. The older highland terrain is intermixed with younger, smoother plains; it is dotted with mountains, volcanoes, massifs with debris aprons, and is intersected by several outflow channels. This work includes a comprehensive survey of images from the Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) of the Reull Vallis region. Through crater counts and stratigraphic analyses, the precise interactions of these various terrains is studied. It is clear that the same processes affect these terrains and their histories are inter-related. By studying not only the youngest surface features, but the geologic history of the entire region, we can gain a better understanding of the continuing activity in the area. Water plays a primary role in the geologic history of this region [1]. Aside from the outflow channels, water has also influenced the evolution of the volcanoes and the debris flows. We hope to gain a better understanding of the sources of the water, as well as any present content, through this study.

Using the Hartmann crater counting methodology [4], we have obtaines crater population data for many MOC images. Counting craters on MOC images tends to give small statistics. To make these data more robust, we count multiple images over similar terrains. The counts on each image are then plotted together to see how well they match up. In most cases, they overlap very clearly. In that case, the counts are then summed together, giving counts of a larger, but not necessarily contiguous area. This region contains four major outflow channels: Reull Vallis, Harmakhis Vallis, Dao Vallis, and Niger Vallis. Studies of the latter two are underway. Reull Vallis extends for ~1500 km through terrains of varied ages and morphologies, and there is evidence for multiple flow events. The floor of the channel contains infill deposits with pits and lineations that parallel its walls, suggesting possible ice flow activity. Crater counts show an age of the floor material on the order of 100 My, which is also very close to the age we found for the surrounding plains. The debris aprons, previously mapped by Crown [3] are clearly very young features. MOC imagery shows few unmodified craters on the debris flows. Distinct, overlapping flows are also evident, which indicates multiple, discontinuous movements down the slopes. The crater counts of the debris aprons show a distinct pattern that differs from almost any other region we have analyzed; the pronounced flattening of the curve at smaller diameters suggests either multiple episodes of flow, with different crater populations on neighboring flows, or even continuous mass movement down the slope.

The geologic history of this region is highly complex, with clear interactions between the various landforms. By using crater counting techniques, we can gain a better understanding of these processes.

References: [1] Mest S. C. and Crown D. A. (2001) Icarus, 153, 89-110. [2] Crown D. A. et al. (1992) Icarus, 100, 1-25. [3] Crown D. A. et al. (2002) LPSC XXXIII, Abstract #1642. [4] Hartmann W. K. and Neukum G. (2001) Space Sci. Rev., 96, 165-194.

Whispers from the Proterozoic Ruin Granite: Possible down-dip extensions of previously mapped Laramide reverse faults into crystalline rocks in the Tortilla Mountains, Arizona

Deb Bryan
Department of Geosciences, University of Arizona, Tucson, AZ 85721
Email: debbryan@geo.arizona.edu

Proterozoic Ruin Granite is exposed in the Tortilla Mountains, 120 km north of Tucson, Arizona. The Tortilla Mountains have a complex history of multiple episodes of Proterozoic intrusion, Laramide magmatism, Proterozoic and Laramide hydrothermal alteration and Tertiary normal faulting with associated tilting which is still not fully understood. In the study area, the Proterozoic Ruin Granite (1.4 Ga), previously mapped as a single unit exhibits several textural phases and is intruded by sheets of Proterozoic diabase (1.1 Ga) and late-Laramide rhyodacite dikes. Current mapping as an Independent Study with the Center for Mineral Resources and with the EDMAP program has provided new information. Evidence from the attitude of Tertiary sedimentary rocks on the eastern side of the mountain range suggests that the entire range is tilted on its side, top to the east. Recent mapping of Tertiary sedimentary rocks and bedrock exposures indicates that the 90° of net rotation was produced by many episodes of normal faulting and associated tilting. (GeoDaze 2003 abstract by Dave Maher et al) Moreover, new mapping suggests that the range also may have been affected by early Laramide-age reverse faulting, prior to emplacement of the Teacup Pluton (new U-Pb date of 73 Ma) and its associated rhyodacite dikes. (GeoDaze 2003 abstract by Gibbons et al,) The inferred reverse faults place Ruin Granite directly on Ruin Granite and display local ductile fabrics. These reverse faults appear to cut off sheets of Proterozoic diabase, which are then shown repeated across the map area before being transected by the late-Laramide rhyodacite dikes. The hypothesis of Laramide reverse faults in crystalline basement is supported by the occurrence of inferred Laramide-age reverse faults involving Proterozoic and Paleozoic sedimentary strata structurally up section to the east. In addition to the above-mentioned ductile deformation and hydrothermal alteration, the Ruin Granite also occurs as brecciated masses lying against unaltered undeformed Ruin Granite. The brecciated rocks of uncertain origin contain very angular clasts, seemingly formed by some form of brittle deformation. Further examination of brecciated Ruin Granite may shed new light on the structural history of the area.

Geophysical and GIS investigation of Black Mesa Basin, northeastern Arizona: Implications to Natural Resource Management

Robert R. Casavant1, Justin Manuel1,*, Mark Gettings2 and Shanda Wagner1
* presenter
1Department of Mining and Geological Engineering, University Of Arizona, Tucson, AZ
2U.S. Geological Survey, Tucson, AZ
Email: jmanuel@email.arizona.edu

The Black Mesa Basin, in northeastern Arizona, occupies most of the southwestern portion of the Colorado Plateau and encompasses a majority of the Navajo and Hopi Reservations. Previous field studies and laboratory models infer the presence of a coarse network of regional, deep-seated northeast- and northwest-trending fracture zones beneath the exposed Mesozoic rocks. Determination of fracture zones was based largely on morphological discontinuities, alignments of exposed Laramide-age fold structures and Cenozoic volcanic centers.

Our recent geological and geophysical analysis validates this, however, we interpret the fracture zones to represent deep-seated basement fault zones. Image processing of residual aeromagnetic and isostatic gravity maps reveal discontinuous, regionally linear, anomalously steep gradient lineaments trending northeast, northwest and north. These lineaments support a basement fault interpretation and are exhibited by the well documented Mesa Butte and Bright Angel fault zones. These faults zones, which are more numerous than previously documented, define blocks of variable dimensions in a dense mosaic arrangement. Some zones have undergone periodic reactivation, whereas, others exhibit en echelon patterns suggesting wrench faulting.

A GIS analysis integrating basement fault fabrics with surface drainage patterns, groundwater movement and the structural and stratigraphic architecture of Mesozoic and Paleozoic formations reveals that deep faulting plays a profound role in the continuing geologic and hydrologic evolution of the region. Integrating deep structure into future geologic and hydrologic models could improve the characterization and management of natural resources on the Navajo and Hopi Nations.

Eastern Whetstone mountains fault model investigation

Scott Geauner1, Ross Waldrip2 and Robert R. Casavant1
1Department of Mining and Geological Engineering, University of Arizona, Tucson, AZ
2Department of Geosciences, University of Arizona, Tucson, AZ
Email: sgeauner@email.arizona.edu

Kartchner Caverns State Park, located in the Whetstone Mountains 13 km south of Benson, is an isolated block of Paleozoic limestone, referred to as the "Kartchner block". The enigmatic block is downthrown to the east juxtaposing the Mississippian Escabrosa Limestone against Precambrian alaskite.

Substantially more faulted than previously mapped, our recent studies also reveal the presence of oblique normal faulting and shearing, which appear to characterize major faults that cross the block. These faults and shear characteristics can be located on the surface and within the caverns. Their origin may relate to Cenozoic-age seismic events that resulted in transtensional deformation throughout the southeastern Arizona and the Northern Sonora region. Fault gouge, anatomizing patterns, oblique normal rake, and fault intensity provide evidence of shearing across the block suggesting a new model that incorporates a minor strike-slip component.

Testing for this model will include a detailed characterization of footwall deformation immediately to the west and northwest of the block and along the eastern flank of the Whetstone Mountains. Fault mapping will be integrated with regional and local gravity and aeromagnetic analyses. Aerial photograph interpretations and fluvial geomorphic indices will be used to guide the field mapping of exposed and buried faults. The additional surface mapping will help to a better reconcile regional structural trends and contribute to an improved understanding of the tectonic processes that shaped the Basin and Range Province of southeast Arizona.

Multiple episodes of magmatism and metasomatism in the Tortilla Mountains revealed by Tertiary crustal extension, Southeast Arizona.

Stacie Gibbins, Julie Hamblock, Eric Jensen, Chao Li and Dave Maher

In the Tortilla Mountains of southeast Arizona, Tertiary extensional faults have tilted crustal blocks on the order of 90¼ to the east. In the vicinity of Grayback Mountain (northern Tortilla Mountains) this tilting has exposed a portion of the crust to paleo-depths on the order of 10km. This has presented an extraordinary opportunity to study, in map view, a cross section through several magmatic-hydrothermal systems from shallow to deep levels. Important igneous lithologies exposed in the Grayback area include (1) 1.4Ga Ruin Granite, (2) 1.1Ga diabase sills, (3) 73 Ma Teacup Pluton and related rhyodacite porphyry dikes, and (4) younger Laramide (?) hornblende andesite dikes. Field mapping, complemented by select lab work, reveals a complex history of multiple intrusive phases and related hydrothermal alteration associated with both the Ruin and Teacup magmatic events.

Detailed mapping of the fault block has identified multiple igneous phases and their time-space distribution in the Ruin Granite and Teacup Pluton. The Ruin Granite is comprised of: (1) a megacrystic K-feldspar granite, (2) an equigranular granite, (3) a porphyritic granite (a finer-grained version of the megacrystic granite(?)), and (4) an aplitic granite. The Teacup Pluton is comprised of: (1) a bio-hbl granodiorite, (2) a bio(( hbl) granodiorite, (3) a musc-bio granodiorite, (4) a bio-hbl monzodiorite, (5) a garnet-musc granite with abundant aplites and pegmatites, (6) rhyodacite porphyry dikes.

We were able to differentiate and map hydrothermal events related to Proterozoic magmatism from those related to Laramide magmatism. Alteration associated with the hydrothermal system(s) of the Ruin Granite includes veins of: (1) qtz + tourmaline(± Kspar ± musc), (2) qtz + Kspar, (3) specular hematite + (Mn-rich) calcite(cc) + montmorillonite, and (4) late calcite. These veins are truncated by the Teacup bio-hbl granodiorite. Alteration associated with the Teacup pluton includes: (1) High-temperature K-silicate alteration (Kspar-bio-qtz) observed near the cupola of the pluton (now exposed to the east due to rotation), (2) sericitic (qtz-ser-py) alteration lateral to the K-silicate alteration (north and south) and in the direction of paleo-up (farther east), (3) low-temperature, epidote-rich alteration outward from the cupola (north and south), and, related to subsequent phases of the Teacup pluton intruded at deeper levels (farther west), (4) renewed K-silicate alteration (Kspar-qtz) and (5) sheeted greisen veins (qtz-course musc-py).

Zircons from two phases of the Teacup pluton (the oldest and one of the youngest intrusions, based on cross-cutting relationships) were dated using the laser ablation ICP-MS technique at the University of Arizona. The older, abio-hbl granodiorite, yielded a date of 73.8 ± 3.1 Ma and the younger, a musc-bio granodiorite yielded a date of 72.7 ± XXXXXXXXXX Ma. This places the timing of crystallization of the Teacup Pluton 10Ma earlier than previously reported K-Ar ages.

The occurrence of multiple intrusions and hydrothermal systems during the Laramide reveals a complexity that has not previously been recognized or associated with Laramide magmatism. New mapping of intrusive phases and related alteration can be used to reconstruct the complex structural history in the region. Yields a better understanding porphyry related hydrothermal systems (can make excellent observations at various levels in the crust)

(see also abstract by Maher, et. al., this volume)

This work was completed during the Spring of 2002 as part of an EDMAP-supported (USGS educational mapping program) course at the University of Arizona. Mark Barton, George Gehrels, David Johnson, and Eric Seedorff also contributed to the mapping, geochronologic, and other aspects of this study.

Use of seismic attributes in gas hydrate reservoir interpretation, North Slope, Alaska

Casey Hagbo and Roy Johnson
Department of Geosciences, University of Arizona, Tucson, AZ 85721
Email: chagbo@geo.arizona.edu

Gas clathrates, commonly known as methane or gas hydrates, are an ice like crystalline solid composed of water and natural gas, primarily methane. Gas hydrates occur in the shallow subsurface where both water and gas are present within low temperature and moderate pressure regimes. The shallow subsurface geology of the North Slope is structurally dominated by a broad antiform, known as the Barrow Arch, and is riddled with a myriad of high angle normal faults trending roughly north south and east west. In addition to the complex structure, the hydrate bearing units are predominantly fluvial and northward prograding deltaic strata. The complexity of the local geology coupled with the lack of a consistent amplitude anomaly associated with hydrate occurrences make simple horizon interpretation of hydrates difficult to impossible. In order to gain a better understanding of the hydrate distribution as well as a clearer picture of the local geology, seismic attributes are being used in conjunction with traditional horizon to well tie interpretation techniques. Several of the attributes, based in the Hilbert Transform, can yield information about the physical properties of the hydrate bearing units. For example hydrate layers may have an anomalous frequency response based on their relatively high acoustic velocity. Delineation of high angle faults and possible channel deposits are aided by the use of calculated coherency and edge detection volumes. Coherency and edge detection volumes are essentially a measure of trace to trace similarity, so discontinuities in the seismic data are brought into tighter focus. The use of these attributes as well as others yields a clearer picture of hydrate distribution as well as a more accurate structural model. This poster was prepared with the support of the U.S. Department of Energy under Award No. DE-FC26-01NT41332. However, any opinions, findings, conclusions, or recommendations expressed herein are those of the author(s) and do not necessarily reflect the views of the DOE.

Digital Earth natural disaster readiness activity

Nievita B. Hartness1, Martin J. Seneca2, Katie L. Nealeigh3, S. Raj Chaudhury4, Waldo J. Rodriguez5, Barbara J. Cooper-Pabis6 and Kerry Lee6
1Department of Geosciences, University of Arizona, Tucson, AZ
2Department of Mathematics, Northeastern Illinois University
3Department of English, Wright State University
4Department of Physics, Norfolk State University
5Department of Atmospheric Sciences, Norfolk State University
6BEST Lab, Norfolk State University
Email: nhartnes@geo.arizona.edu

We have developed an interactive learning module, designed for the non-science major college student, which involves analysis of the effects of the 1997-1998 El Niño Southern Oscillation anomaly on natural disasters in the United States. Case studies are presented on flood, fire and drought. Our methods involved data mining information available on government, educational and public information websites and the creation of qualitative and quantitative exercises. The module will be tested with the target student population during the Spring of 2003.

Holocene fault activity beneath the Great Salt Lake

Andrew M. Hennes and Roy A. Johnson
Department of Geosciences, University of Arizona, Tucson, AZ 85721
Email: ahennes@geo.arizona.edu

Fault scarps along the Wasatch Front evidence seismically active normal faults that accommodate east-west extension along the eastern margin of the Basin and Range province. These well-defined normal faults accommodate large offsets that juxtapose Precambrian rocks of the Wasatch Range against thick syntectonic Tertiary strata in the Salt Lake Basin. Mohapatra and Johnson (1998) identified a system of similar listric normal faults with large offsets in seismic reflection data from beneath the Great Salt Lake. Offsets near the surface on these listric faults are evident in several seismic profiles from the Great Salt Lake and suggest displacement has continued through at least the Tertiary. Some of these young faults may in fact have movement recent enough to breach the surface and produce a scarp even in the relatively rapid sedimentation of this sub-aqueous environment. Fathometer-recorded water depths collected during this dense seismic program in the Great Salt Lake allow a unique opportunity to construct a detailed bathymetric map of the Great Salt Lake. Geostatistical analysis of the water depth reveals the expected relatively smooth overall bathymetric surface of the floor of the Great Salt Lake except for several abrupt changes in the bathymetry. A plot of the gradient magnitude, or rate of change of the bathymetry, indicates several linear features with steep surfaces much like fault scarps that trend along the regional fault fabric. These anomalous surface gradients correlate well with seismically defined normal faults that run along the western margin of Promontory Point and Antelope Island, as well as along the northern side of Carrington Island, suggesting that these faults do breach the surface. Development of a fault scarp in a flat, shallow, internally drained basin indicates very recent fault activity along large faults beneath the Great Salt Lake.

Middle-Cambrian faunas of the Weeks formation, west-central Utah

Hector R. Hinojosa
University of Utah, Salt Lake City; Summer Research Opportunity Program 2001
Email: pachuco411@hotmail.com

The North Canyon Quarry of the Weeks Formation crops out in the House Range of Utah. It is a sequence of an inner belt of marine sandstone and shale, an intermediate belt of carbonate rocks, and an outer belt of mud and breccias with exceptionally well-preserved polymeroid trilobites, in its uppermost section. The trilobites date from the upper-middle to the lower-upper Cambrian, and are important to stratigraphic zonation in western North America because amplify the understanding of geologic processes in west-central Utah. Modocia (Walcott) from the upper part of the Weeks formation allows correlation with the upper Cambrian Kulyumbe stage, in Igar region of northwestern Siberia. L. laevigata, from the lower part of the formation correlates with strata in: 1) the uppermost Bolaspidella zone and much of the Cedaria Zone in North America; 2) the L. laevigata zone of North Greenland, which ranges throughout Formation T2 of the Tausens Iskappe Group; 3) the Westergard's Solenopleura brachymetopa zone in Sweden, and the upper subzone with his zone of L. laevigata; 4) the lowest observed occurrence in the Huaquio Formation, Hunan China, and 5) Antarctica, Argentina, Australia, Canada, Kazakhstan, Siberia.

Construction of the upper Sabino Canyon dam

Dave Hohman
Department of Geosciences, University of Arizona, Tucson, AZ 85721
Email: hohman@email.arizona.edu

In the 1930's a large dam was to be constructed in Upper Sabino Canyon. The road that is there now was built for the construction crews to build the dam. This dam would create a large lake for boating, swimming and other recreation. Funding issues led to the cancellation of the project.

Using digital elevation models (DEM's) of Sabino Canyon and its surrounding area, along with computer mapping programs, my project digitally finishes the construction of the dam. I explore what the landscape of the area would be like today with a lake and also take a look at the potential future consequences of drastically changing the river profile.

The poster will give a history of the dam project, show the canyon as it is today, show the canyon as it would be today with a lake, and show what could happen in the future to the river profile and how that would affect Tucson.

Plutons on end: A new look at the Proterozoic Ruin Granite, Tortilla mountains, Arizona

Steven Hubbs
Department of Geosciences, University of Arizona, Tucson, AZ 85721
Email: shubbs@geo.arizona.edu

In the northern Tortilla Mountains (~100 km north of Tucson) the middle Proterozoic Ruin Granite (1.440 ± 0.020 Ga U-Pb; Silver et al., 1981) has been previously mapped as a single block of unfaulted, undifferentiated quartz monzonite. Faults systems that offset overlying strata are usually not indentified in these Proterozoic plutonic units because of the difficulty in recognizing structural offset in what was regarded as a relatively homogenous plutonic body. New field mapping has identified in detail multiple textural units within the Ruin Granite and numerous types of superimposed hydrothermal alteration, the latter related to both Ruin-age and Laramide alteration. Laramide alteration is interpreted to be associated with the nearby Teacup Granodiorite intrusion, recently dated at ~73 Ma (U-Pb; G. Gehrels et al., unpublished data), and is part of a system that includes the Kelvin and Riverside porphyry copper prospects.

Currently recognized textural phases of the Proterozoic Ruin Granite include: (1) Megacrystic granite (K-feldspar megacrysts locally >4 cm), (2) Porphyritic granite (quartz phenocrysts, locally with strongly lineated qtz), (3) Pegmatitic granite (quartz-K-feldspar ± tourmaline), (4) Aplitic granite (aplitic groundmass of quartz-K-feldspar), and (5) Equigranular-seriate granite (variably biotite-bearing). The superimposed alteration includes veins of quartz + K-feldspar + tourmaline of probably Proterozoic age and multiple zones of sericitic, biotitic, and chloritic alteration of probably Laramide age. The Ruin Granite in the study area is anything but homogenous.

Nearby Tertiary strata exhibit locally extreme tilting, with some beds rotated to ~90°. Indeed, the northern Tortilla Mountains provide a rare opportunity to view a pluton on its side, where paleodepth can be viewed to several kilometers in well-exposed terrain. Evidence for extensive Tertiary normal faulting within the Ruin Granite includes: (1) The presence of heavily gouged zones of varying thickness and (2) the juxtaposition of contrasting igneous phases and Laramide alteration styles. Field evidence indicates faults in widely varying orientations, suggesting multiple generations of crosscutting normal faults. The structural story of the study area is of special interest in light of the copper resources of the area, which includes the nearby Ray Cu-porphyry deposit. Recognition and mapping of Tertiary faulting in the plutonic parts of the Proterozoic section is essential to regional reconstruction.

Obstacles preventing K-12 science teachers from implementing GLOBE in their classrooms

Kathy Likos and Michelle Hall-Wallace
Department of Geosciences, University of Arizona, Tucson, AZ 85721
Email: klikos@geo.arizona.edu

GLOBE (Global Learning and Observations Benefiting the Environment) is an international environmental and science education program that involves K-12 students in collecting and interpreting environmental data from their local area. Students use universal protocols (that have been developed by GLOBE primary investigators/scientists) to collect data in four major areas: soil, water, land cover, and atmosphere. The data can then be entered into a database that is accessible to students and researchers worldwide via the Internet. The goals of the program are to enhance the environmental awareness of individuals throughout the world, contribute to scientific understanding of the Earth, and help all students reach a higher level of achievement in science and mathematics. Teachers who choose to implement the GLOBE program in their classrooms are required to attend a 20-30 hour training session to learn about the program, the data collection protocols, and content knowledge on each of the investigation areas. Approximately 30-40 teachers are trained per year throughout southeastern Arizona. However, after earning certification in GLOBE, few teachers implement any part of the program in their classrooms. Discussion forums and surveys are being conducted to investigate what obstacles prevent such a large percentage of GLOBE certified teachers from implementing the program. We suspect that common obstacles include lack of funds for specified equipment, challenges integrating GLOBE program goals with the curriculum, and lack of initiative to start the program due to the overwhelming amount of material covered in the training sessions. Surveys to determine whether and how the GLOBE program affects teachers' perspectives of the nature of science will be developed as well. Lessons learned from evaluating the GLOBE program will be used to adapt the program to better meet the needs of K-12 teachers and to increase the program implementation in K-12 science classrooms.

Synextensional sediments record progressive faulting and tilting in the Tortilla Mountains, AZ

David Maher1, Aaron Martin2, Deb Bryan1, David Mauel3 and Steven Hubbs1

1 Center for Mineral Resources, Department of Geosciences, University of Arizona, Tucson, AZ 85721
2 Department of Geosciences, University of Arizona, Tucson, AZ 85721
3 Department of Geological Sciences/MSC 3AB, New Mexico State University, P.O. Box 30001, Las Cruces, NM 88003
Email: geodave@mindspring.com

Tertiary terrestrial sediments were deposited in normal fault-controlled basins in the Tortilla Mountains west of Ray, AZ from about 25 Ma to about 18 Ma. These deposits are classic growth strata, with interfingered debris flow, fluvial, lacustrine, and landslide megabreccia deposits exhibiting progressively shallower dips in younger sediments as down-to-the-west faulting and rotation of crustal blocks occurred. The sediments were deposited disconformably on the bedrock, and locally the oldest beds are tilted more than 90° from paleo-horizontal. The sediments are composed of variably mixed older rocks, including altered and mineralized rocks related to various hydrothermal systems. The study area is in the vicinity of several hydrothermal systems, including the Teacup (Kelvin) and the Ray porphyry copper systems. The Ray system is the largest known with approximately 6.5 million metric tonnes of total contained copper.

A measured section about 1900 meters thick, in conjunction with reconnaissance mapping of sedimentary successions in the Tortilla Mountains, provide insights into the tectonic environment at the time of deposition, source areas for sediment, and depth of erosion of those source areas.
From 100 to 420 meters above the base of the section, about ten large-scale landslide megabreccia deposits occur. These moderately to locally very thick (over 100 meters) oligomictic sediments are brecciated, but still exhibit original stratigraphic features at a larger scale, suggesting large-scale mass movement. Each megabreccia lithosome is monolithologic, and the individual bedrock unit that was the source can usually be identified. The landslide blocks dip about 60° to 50°. We suggest, therefore, that the source area for the landslides was the hangingwall, which had been tilted about 30° to 40° at the time the landslides occurred. At this degree of tilt, bedrock stratigraphic horizons would become unstable slip planes.

The monolithologic megabreccias separate the basin fill into two genetically different successions. Sediments within and beneath the megabreccias are composed entirely of sedimentary-lithic clasts derived from Paleozoic and Proterozoic strata widely exposed in southern Arizona. Cobble to boulder conglomerates beneath the megabreccias were deposited in braided streams with dominant paleoflow to the southeast. All units above the megabreccias are dominated by volcanic-lithics, with very minor input from Paleozoic and Proterozoic sources. Gravelly braided stream deposits with paleoflow to the northeast are interbedded with debris flow deposits in the interval 420 to 940 meters. Above 940 meters, the debris flows become tuffaceous, and several ash fall tuffs are present. Interfingering of braided stream and debris flow facies suggests deposition on alluvial fans. Paleoflow direction turns to the northwest in the upper part of the section.

Reconstruction of a cross section (Seedorff, 2002) utilizing local and regional bedrock contact relationships shows several sets of cross cutting faults and progressive tilting during extension. The pattern of dip changes within the measured section suggests that the process of tilting (resulting in the deposition of growth strata) was episodic, separated by periods of relative "tectonic quiescence". These periods of development of growth strata may correlate to the generation and movement of new faults.

A new look at middle Tertiary dismemberment and rotation of Laramide porphyry systems in southern Arizona

David Maher, Eric Seedorff and Mark Barton
Center for Mineral Resources, Department of Geosciences, University of Arizona, Tucson, AZ 85721
Email: geodave@mindspring.com

In southern Arizona, crustal extension has dismembered, displaced, and rotated numerous porphyry copper and associated igneous systems. From Globe-Miami to San Manuel, re-evaluation of well-mapped quadrangles and new observations permit an improved assessment of middle Tertiary crustal extension and its profound impact on the distribution of igneous-related Laramide copper mineralization. This provides an improved framework for exploration for hidden mineral deposits and development of accurate deposit models.

The Globe-Miami and San Manuel to Kelvin areas apparently lie within individual tilt domains where on the order of 100% extension occurred on multiple generations of faults that collectively cut and rotate paleo-up from <10 to >90°. Regional tilt domains overlap in the area near Ray, Arizona. Here, multiple generations of faults with opposing displacement directions result in a number of smaller fault blocks that underwent a more complex tilt history. The present orientation of individual blocks is the sum of the tilts of the overlapping fault events (see also abstracts by Gibbins, et al. and Maher, et. al., this volume).

Models of hydrothermal alteration in porphyry systems were strongly influenced by exploration-driven work in this region in the 1950s and 1960s when dismemberment of porphyry systems by normal faults was first recognized. Evolving understanding of regional-scale, post-mineral structure remains critical to reconstruction of both hydrothermal and related igneous systems. Key issues in this ongoing study include determination of paleo-up, identification of all deposit fragments (including eroded portions), and clarifying what constitutes variation in mineralogical zoning patterns versus structural juxtaposition of different portions of hydrothermal systems. Tertiary extension was also important to the supergene history through rapid exhumation of deposits and modification of groundwater flow patterns.

Numerous complex geologic contact relationships are seen in map view as approximate paleo-cross sections and establish the structural pierce points in the faulted blocks that have been displaced more or less laterally relative to the present day surface. The structural pierce points observed in the study in southern Arizona allow the reconstruction of numerous fault blocks that contain mineral deposits, and highlight areas that may contain faulted segments of known deposits.

Given that many of the mineral deposits in southern Arizona are fault-bounded, exploration for deposits in this terrain has long utilized structural interpretations. A revised interpretation of regional extension opens windows for finding hidden deposits or displaced fragments of known deposits. Application of regional structural understanding to the deposit scale also has substantial economic implications from feasability through production. For example, understanding faults within deposits is key to generating accurate reserve calculations, mine planning, and anticipating dilution effects and predicting ore-waste boundaries for ore control.

Regional characterization of the Cretaceous Nanushuk group: Preliminary assessment for CBM potential in northern Alaska

Keith Mitchell, Robert R. Casavant and Justin Manuel
Department of Mining and Geological Engineering, University of Arizona, Tucson, AZ
Email: keithm@email.arizona.edu

This NSF undergraduate research experience (REU) will initiate a preliminary regional geological characterization of the Cretaceous-age (Brookian) Nanushuk Group in Arctic Alaska. The goals of the study include investigating the role of structure on the distribution, storage potential and effective diffusivity of CBM (coalbed methane) resources across the NPRA (National Petroleum Reserve of Alaska) using 3D interpretation workstation in the newly developed Subsurface Characterization and Imaging Lab (SCIL) in MGE. We are proposing that regional syndepositional faulting, related to tectonism and kilometer-scale denudation across the Arctic Alaska Terrane, could be related to the quality and distribution of gas-rich coal seams. We hypothesize that North Slope coal deposits may be more abundant and fractured, thicker and thermally matured as a result of sediment accommodation and hanging wall deformation associated with basement faulting and renewed thrusting events.

The coal-bearing Nanushuk Group is a sequence of fluvial-deltaic to shallow marine deposits that has been studied extensively for its oil and gas potential. The studies include characterizations by the U. S. Geological Survey (USGS), Alaska Division of Geological and Geophysical Surveys (ADGGS) and a number of exploration petroleum companies. The overall sequence consists of interfingering parasquences of interbedded conglomerate, sandstone, siltstone, shale and coal. Two- and three-dimensional reflection seismic data reveal that the sequence thins to the north and east, transitioning basinward into marine shales. In some locations, it is indistinguishable from the clastic-rich shale-rich topsets of shale-dominated clinoforms in the underlying Torok Formation. Surface and subsurface studies of the petroliferous and coal-bearing Nanushuk Group continue to underpin reassessments of energy resources throughout the vast NPRA. Current petroleum exploration activities within the eastern portion of the NPRA have included the Nanushuk clastics as one of several target horizons.

Our preliminary study will reassess regional variations in gross thickness of Nanushuk and relate it to the distribution and quality of coal deposits. Published two-dimensional reflection seismic will be used to construct gross isopachs and structural maps of the unit. Outcrop and well log data will serve as control points for verifying formation thickness and variations in coal thickness and quality. Results of this study will be interrogated in light of Cretaceous- and Tertiary-age basement fault reactivation as indicated by stratigraphic data and apatite fission track studies. Coal thickness, thermal maturation and fracturing will be key factors in the anticipated exploration and reservoir engineering of CBM resources throughout northern Alaska.

Bacterial adhesion in the subsurface environment: Investigating the role of extracelluar polysaccharides

Sanjai J. Parikh, Anselm Omoike and Jon Chorover
Department of Soil, Water, and Environmental Science, College of Agriculture,University of Arizona, Tucson, AZ
Email: sjparikh@ag.arizona.edu

Molecular-level interactions of bacterial adhesion to surfaces have not been adequately explained. Understanding the surface chemical reactions of bacterial adhesion is required to manipulate and control the adhesion process. Bacteria adhering to natural surfaces can both be beneficial and detrimental. In aquatic environments bacterial adhesion can be utilized to improve water quality. These reactions are controlled by surface chemical reactions between the exterior of bacteria cells, the physical characteristics of the surface, and solution chemistry. The exterior surfaces of bacterial cells comprise extracellular polymeric substances (EPS) and lipopolysaccharides (LPS) (gram negative bacteria only) that likely are crucial in the adhesion process. Studies investigating the role of both EPS and LPS in the initial moments of adhesion increase understanding of, and the ability to predict microbial binding. This in turn helps predict the fate and transport of bacteria cells and environmental contaminants. In situ experiments monitor the adhesion and growth of bacteria on a Ge crystal using attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy.

Use of Attenuated Total Reflectance/Fourier Transform Infrared Spectroscopy allows for non-destructive, real time, in situ observation of bacterial adhesion. Using this technique to study the adhesion of Pseudomonas aeruginosa, wild type (PAO1) and alginate (negatively charged extracellular polymeric substance) over-producer (PDO300), we have observed that the presence of excess alginate reduces initial adhesion. Proteinaceous materials (1550 cm-1 and 1650 cm-1) are important fingerprint regions in monitoring the adhesion of this bacteria. A general trend of increased intensities for PAO1 is observed, particularly for the amide I (1650 cm-1) and amide II (1550 cm-1) regions of the spectra. PDO300 intensities do not increase significantly, consistent with less adhesion. For PAO1, increased cell density is well correlated with increased IR absorbance of bacterial surface functional groups. The over production of alginate by PDO300 likely reduces the initial attachment of P. aeruginosa to the Ge substratum. We believe that positively-charged regions (proteins) control the initial adhesion of P. aeruginosa to the Ge crystal. To compliment this research batch experiments will be conducted to investigate the kinetics and effect of solution chemistry on adhesion of LPS with environmentally relevant surfaces.

Evidence for Himalayan Paleozoic deformation through magmatic intrusion analysis

Guy Pinhassi, George E. Gehrels, Bishal N. Upreti and T.P. Ojha
Department of Geosciences, University of Arizona, Tucson, 85721, AZ
Email: guyp@swfo.arizona.edu

Cross-cutting relationships among hosting neoproterozoic schists and granitic dikes, provides new age constraints and important information on the importance of early Paleozoic deformation in the Himalayan orogenic belt. In the Kathmandu nappe, Bhimphedi Group schists are intruded by 2 phases of granitic dikes. Older dikes that have a foliation are 486- 476 ± 18 Ma in age, whereas a non-foliated, cross-cutting dike is 472 ± 12 Ma in age (ages from U-Pb in zircon). These dikes may indicate the cessation of early Paleozoic deformation in the crystalline nappes of the Himalayan orogenic belt.

Chronology and sedimentology of major lake-level fluctuations on the Southern Bolivian Altiplano

Christa Placzek1, Jonathan Patchett1, Jay Quade1 and Julio Betancourt2
1Department of Geosciences, The University of Arizona, Tucson, Arizona 85721
2U.S. Geological Survey, 1675 West Anklam Road, Tucson, Arizona, 85745
Email: cplaczek@geo.arizona.edu

A key controversy in South American paleoclimatogy centers around conflicting lake histories based on shoreline and downcore evidence from the Bolivian Altiplano. The Altiplano depression, spanning 14 to 22°S (~3800 meters asl), is defined by three large lake basins, Lake Titicaca to the north, Lake Poopo in the center and the salt pans of Coipasa and Uyuni to the south. These basins have coalesced into one megalake >90 m deep and ~50,000 km2 at least twice in the Quaternary, but the exact timing is disputed. At stake in these megalake chronologies is the influence of global temperature and the long-term history of the South American Summer Monsoon (SASM), which could be sensitive to variations in seasonal insolation over precessional time scales and changes in tropical and meridional SST gradients. Radiocarbon dates from calcareous crusts and mollusks in both cores and shoreline deposits in the Uyuni-Coipasa Basins suggest that Paleolake Tauca persisted between 19 and 12 ka, with a highstand at ~16 ka. In contrast, a radiocarbon chronology from total organic carbon suggests that Paleolake Tauca persisted between 26.1 and 14.9 ka, centered on a peak in summer solar insolation (~21 ka). This latter chronology argues for direct forcing of the SASM by summer insolation over the Altiplano, the former calls for other forcing such as changing SST gradients. The timing of an older Paleolake, called Minchin, could help discriminate between competing hypotheses. Paleolake Minchin was originally dated between 26 and 30 C14 ka based on shoreline deposits but evidence from two recent cores in Uyuni-Coipasa suggests that Minchin happened before 34 C14 ka.

We propose a chronology for Altiplano megalakes based on U/Th chronology, radiocarbon dating, and shoreline stratigraphy. This approach allows direct establishment of lake level and replication of dates using more than one method. Lacustrine units are manifested as diatomite, tufa, and gastropod-rich sediments. We infer that only two megalake events occurred in the last 130 ka, separated by a well-developed and persistent paleosol. The youngest lake phase dates between 17-12.1 ka, with a maximum lake level at ~15.5 ka; the U/Th and 14C ages are remarkably consistent. U/Th dates from the oldest lacustrine unit fall between 122 and 94 ka. Radiocarbon dates from this unit, however, are as young as 30 C14 ka. The sensitivity of infinite radiocarbon samples to in situ contamination call into question the reliability of previous C14 dates for the Minchin Phase. Our chronology suggests that climatic explanations be reexamined for megalake expansion on the Bolivian Altiplano. For example, during periods of cold global temperature (20-80 ka), thermal forcing of the SASM is probably insufficient to sustain summer rains over the southern Altiplano. On the other hand, higher lake evaporation and evapotranspiration rates, and more persistent drought associated with higher ENSO frequencies, may also prevent lake expansion during interglacials. Hypothetically, megalake expansion should happen during periods of moderate global temperature, cool enough to diminish lake evaporation and reduce evapotranspiration at higher elevations, but warm enough to still drive large-scale monsoonal circulation and summer precipitation over the Altiplano.

Seismic analysis of the space shuttle Columbia disaster

Marie D. Renwald, Tammy K. Baldwin and Terry C. Wallace
Southern Arizona Seismic Observatory, University of Arizona, Tucson, AZ 85721
Email: mrenwald@geo.arizona.edu

On February 1, 2003, the Space Shuttle Columbia and crew were lost during reentry 16 minutes before landing at Cape Canaveral, Florida. Columbia was at an altitude of 200,000 feet over north-central Texas, traveling at 12,500 mph when mission control lost contact and tracking data. Debris from the shuttle was scattered over thousands of square miles of Texas and Louisiana. Investigative efforts are focused on understanding how Columbia broke apart.

Seismic data provides a means of investigating this tragedy. Both sonic booms and atmospheric explosions can be recorded on land-based seismometers. Using NASA's projected flight path for the Columbia, we were able to identify seismic networks and stations that recorded useful data. Comparing data from this Columbia mission to previous shuttle missions allows us to constrain the specific sequence of events during and after Columbia's disintegration. For example, station LTL in Louisiana recorded a sonic boom during reentry of the Columbia shuttle after a mission to service the Hubble Space Telescope in March 2002. This is seen as a high frequency pulse (one to two seconds long) in the seismic record. During reentry of Columbia on February 1, 2003, LTL did not record a sonic boom, but rather, an explosion. The event is approximately 100 seconds long and contains both high and low frequency signal.

The signals can be used to locate the explosion if the velocity of sound is known for the atmosphere. Since the Columbia disaster took place at an altitude greater than 200,000 feet, the model is quite complex because of cold and warm regions. By considering an atmospheric velocity model with data from stations near the shuttle's flight path, we determined the location of the shuttle explosion and correlated arrivals on the seismic records with the sequence of events that led to the shuttle's disintegration.

Engaging and educating via the Web: Designing a national scale outreach effor
t

Marie D. Renwald1, 2, Bryan D. Hance1, Michelle K. Hall-Wallace2
1The IRIS Consortium
2Southern Arizona Seismic Observatory, University of Arizona, Tucson, AZ 85721
Email: mrenwald@geo.arizona.edu

EarthScope is a proposed decade-long, continental scale experiment to understand the structure, formation, and evolution of the North American continent. Data collected from this experiment and the subsequent insights derived from this data will be of inherent interest to scientists, educators, and the general public. For the past year, we have been developing a web-based interface to engage and educate a broad audience with the scientific contributions made by the EarthScope experiment. The result, http://www.earthscope-eon.org, features a suite of tools and interfaces which include the Discovery Map, a dynamic map that highlights ten areas of North America each week which are geologically unique or interesting; the Data section which currently allows users to view real-time seismic and GPS data, and in the future it will allow users access to other geologic data collected from the experiment; and the Research section which allows participating scientists and educators a seamless method of sharing general information and results about individual projects via customized database queries and dynamically generated web pages.

Designing a website which targets a range of users requires a working knowledge of both website programming and design. Issues considered when building the site included designing a logical navigational structure; accounting for browser differences, both in terms of site look and functionality; utilizing current website development tools, such as PHP, MySQL, and RDF feeds, as well as existing geoscience applications like Antelope, an environmental monitoring software package; site maintenance automation; database development; and accessibility for users with a range of internet skills and physical limitations. By accounting for each of these items, we have built a dynamic interface which can be utilized by anyone interested in the EarthScope experiment. Additionally, we feel these efforts can also serve as a model for research groups, both large and small, wishing to make an effective presence on the internet.


What happens to soil when it rains?: Investigations and implications of soil development across a rainfall gradient in Hawaii

Aaron Thompson and Jon Chorover
Dept. of Soil, Water and Environmental Science, University of Arizona
Email: athompson@ag.arizona.edu

At a macro level, you get mud, right? But chemically, the soil changes from a oxygen rich, environment to an oxygen deprived environment as water fills the pore spaces in the soil. This can dissolve Fe and other metals adhered to the iron, greatly influencing the surface properties of soil minerals. Does the amount of rainfall change the influence rock-derived constituents have on an ecosystem? How important are Fe-oxides in regulating nutrient and pollutant cycles? These basic questions impact a myriad of human interactions with our earth's upper crust. Everything we eat comes from and eventually ends up back in the soil. The location of farm fields, the productivity of forests, and the positioning of waste disposal systems all hinge on the type and nutrient status of our soils.

We are using the natural age and climate gradients in the Hawaiian Islands to answer these important questions. From previous aspects of this research, it is clear that a "sweet-spot" in productivity exists in middle-aged soils (~150 ky) and that climate alters this "sweet-spot" towards greater rainfall at younger soils and towards lower rainfall in older soils. Soil iron content is a critical parameter delineating productivity. This current work focuses on the changing role iron plays in ecosystem biogeochemistry as rainfall increases (2.2 to 4.2 meters of mean annual precipitation (MAP)). All sites are on forest soils with similar vegetation, developed from a 400,000-year-old Kula volcanic flow on the island of Maui, HI. At sites with higher rainfall, oxygen concentrations are diminished and previously solid iron dissolves in the rainwater through the process of chemical reduction. At intermediate rainfall sites, this dissolved iron can re-precipitate and form very small (nanoscale) particles. The newly formed particles have very high surface area and are important sorbents for nutrients (e.g., phosphate), pollutants (e.g., heavy metals) and natural organic matter (NOM). This process of reduction (dissolution) and oxidation (precipitation) can be referred to as iron redox-cycling {Fe(III) ßà Fe(II)}. Our preliminary results indicate that fluctuations between reduced and oxidized iron increases the fraction of soil iron available for nutrient and pollutant sorption ("active fraction"). This may indicate that in the "sweet spot" is in part maintained by recycling of iron within the soil profile. If this is indeed the observed result, the implications of this research extend beyond ecosystem and soil biogeochemistry and could offer a method for improving land-based waste disposal systems. The capacity of soil based wastewater disposal systems (such as leach-fields), might be improved by subjecting the soil to several redox fluctuations to increase the "active fraction" of soil iron for attenuating and remediating the waste.

Near-surface seismic imaging across the Pitaycachi Fault, northeastern Sonora, Mexico

Frank H. Wagner, III (Trey) and Roy A. Johnson
Department of Geosciences, University of Arizona, Tucson, 85721, AZ
Email: fwagner@geo.arizona.edu

The Pitaycachi normal fault of northeastern Sonora, Mexico is the source of the 3 May 1887 Bavispe earthquake (Mw ~7.4). This fault bounds the eastern margin of the San Bernardino Valley, extending roughly north-south for over 100 km with fault-scarp exposures from the 1887 earthquake of up to 4 meters. In the fall of 2001, a near-surface seismic survey across this fault was undertaken to attempt to image shallow structures associated with the fault in order to better constrain recent fault activity. Ray-trace modeling and tomographic inversion of first arrivals show that unconsolidated sediments in the footwall are thin (~1 meter) and overlie more consolidated course alluvial-fan sediments. Unconsolidated sediments near the surface in the hanging wall are greater than 8 meters thick and show significant lateral and vertical velocity variations. Total throw on the fault is estimated at over 4000 meters since fault initiation at about 23 Ma, giving a total slip rate of 0.17 mm/yr. Although previous estimates of Quaternary slip rates on this fault are believed to be significantly less, fault activity remains vigorous. The nature of the faulting in the San Bernardino Valley is similar to Quaternary fault scarps flanking numerous basins in southern Arizona, and provides evidence of continued extensional deformation in the southern Basin and Range Province.

Preliminary kinematic study of the "Kartchner block", southeastern Arizona

Shanda Wagner1, Robert R. Casavant 1, Rickard Toomey, III2 and Ginger Nolan2
1Department of Mining and Geological Engineering, University of Arizona, Tucson, AZ
2Kartchner Caverns State Park

A group of structurally isolated hills, composed of mostly Paleozoic limestone formations, resides along the eastern flank of the Whetstone Mountains in southeastern Arizona. The newly-developed 550 acre Kartchner Caverns State Park (KCSP) encompasses several of these hills. The hills comprise a fault-bounded block that is sometimes referred to as the "Kartchner block". Recent mapping and field investigations indicate that the fault density across the block is greater than previously interpreted and that fault kinematics are more complex.

Guided by detailed aerial photo interpretation, field mapping and a re-examination of fault surfaces above and below ground were completed. Our preliminary findings indicate that an undetermined amount of oblique-slip was an important component of the predominate normal faulting that deformed the block. A pervasive oblique component had not been previously documented across the block, except for two faults splays within the caverns. This component is characterized by the prevalence of brecciated and Fe-rich fault zones, anastomozing distribution of some major faults, en echelon arrangement and/or lateral offset of joints and veins, tiled and folded calcite-rich veins, drag folding, and oblique orientations of fault grooves and slickenlines.

How this oblique component relates to the structural evolution of the block and cavern formation is the focus of on-going study. Future results may contribute to an improved understanding of the geologic, geomorphic and hydrologic evolution of the adjacent San Pedro Valley. The research may also prove useful to future cavern management and planning.

Martian dust devil tracks in Argyre Planitia and Hellas Basin

P. L. Whelley, M. R. Balme and R. Greeley
Department of Geological Sciences, Arizona State University, Tempe, AZ, 85287
Email: pwhelley@asu.edu.

Dust devils on Mars are important mechanisms for delivery of dust into the Martian atmosphere. Suspended dust in the Martian atmosphere is estimated to be ~1-2mm in diameter [1,2,3]. Calculations of dust fall-out rate [4,5] imply an ongoing supply of this fine dust to the atmosphere. Wind tunnel experiments [6,7], however, suggest that entrainment of fine dust into the atmosphere requires boundary layer wind speeds exceeding those measured on Mars. Recent experiments using a laboratory scale vortex generator at low-pressure [8,9] show that vortex action (i.e. a dust devil) is more efficient for lifting fine dust than boundary layer winds. Coupled with the many observations of dust devils on Mars [10], these experiments suggest that dust devils are an important contributor to the global dust budget. Characterizing the temporal and spatial distribution of dust devil activity on Mars is essential for gaining an understanding of the Martian surface processes. Several studies have attempted to determine the frequency of active dust devils using Wide Angle [11] and Narrow Angle (NA) [12] MOC images but they only sample a small fraction of dust devil activity. The transient nature of dust devils, the limited spatial coverage of the high resolution images required to resolve them, and restricted viewing times of the Mars Orbiter Camera (MOC) makes their detection serendipitous. However, the passage of dust devils over the surface is inferred to leave surface tracks that remains visible for months longer than the lifetime of the dust devil that produced it. Here we investigate the distribution of dust devil tracks in Argyre Planitia (20o to 50oW; 60o to 30oS) and the Hellas Basin (250o to 320oW; 60o to 15oS).

The study areas were chosen because they a) display a variety of geomorphic units, b) cover a range of elevations, c) are at similar latitudes for seasonal comparisons, and d) contain images with visible tracks. We searched all MOC NA images with resolution 7m/pixel or better from the CAL to E12 phases (March 1999 to February 2002) of the Mars Global Surveyor mission for dust devil tracks. We counted the number of tracks in each image and then normalized by the surface area of the NA strip to determine the density of tracks per square km. In total, we searched 637 images in Argyre and 2037 in Hellas. Results and conclusions: Laboratory experiments [9] suggest that small changes in surface pressure (as would occur between regions of different elevation) might influence the efficiency of dust devil particle entrainment. Hellas shows greater dust devil track abundance at lower elevations, except for the lowest topographic regions. In Argyre most tracks are found around 0km elevation and no clear conclusion on the influence of elevation on track formation can be drawn. In contrast, the occurrence of dust devil tracks strongly correlate with Martian season, and is strongest in spring/summer when insolation is at its peak. From the seasonal differences in dust devil track density we infer that: "summer" dust devil activity starts earlier and continues longer in Argyre; almost all dust devil activity appears to cease in mid fall in Argyre whereas in Hellas, dust devil tracks are still visible until the onset of winter. These occurrences suggest that dust devil tracks form preferentially in Argyre but are covered/erased more quickly than in Hellas. This change could reflect differences in availability of fine materials for dust devils to pick up (and later to cover their tracks) or differences in seasonal weather patterns between the two study areas. In both basins the areas with the highest dust devil track density are found in areas with high TES (Thermal Emissions Spectrometer) albedo. As albedo is commonly correlated with dust abundance this suggests that the areas with the most dust have a higher density of dust devil tracks.

References: [1] Pollack J.B. et al. (1979) JGR 84, 2929-2945. [2] Smith P.H. et al. (1997) Science, 278, 1758-1765. [3] Snook K.J. (2002) LPS XXIII, Abstract #1600. [4] Kahn R.A. (1992) in 'Mars' edited by Kieffer, H.H. et al. [5] Smith P.H. and Lemmon M.T. (1998) JGR 104, 8975-8985. [6] Greeley R. et al. (1981) Geol. Soc. Amer., Special Paper 186, 101-121. [7] Iversen J.D. and White B. (1982) Sedimentology, 29, 111-119. [8] Balme M.R. et al (2002) EOS Trans. 83 (47) Fall Meet. Suppl., P41A-0334. [9] Greeley R. et al. (2002) JGR in press. [10] Edgett K.S. and Malin M.C. (2000) LPS XXXI, Abstract #1073. [11] Biener K.K. et al., (2002) LPS XXXIII, Abstract #1048. [12] Fisher J. et al. (2002) EOS Trans. 83 (47) Fall Meet. Suppl., P41A-0332.